\u4e09\u57fa\u78f7\u7684\u7075\u6d3b\u6027\u5206\u6790\uff1a\u5b9a\u5236\u5316\u9879\u76ee\u4e2d\u7684\u660e\u661f\u5206\u5b50<\/h1>\n

\u5728\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u4e09\u57fa\u78f7\uff08Triphenylphosphine\uff09\u5c31\u50cf\u4e00\u4f4d\u591a\u624d\u591a\u827a\u7684\u827a\u672f\u5bb6\uff0c\u65e2\u80fd\u626e\u6f14\u6e29\u548c\u7684\u50ac\u5316\u5242\uff0c\u53c8\u80fd\u5316\u8eab\u4e3a\u5f3a\u5927\u7684\u914d\u4f53\uff0c\u8fd8\u80fd\u6210\u4e3a\u5408\u6210\u53cd\u5e94\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u5e2e\u624b\u3002\u4f5c\u4e3a\u6709\u673a\u78f7\u5316\u5408\u7269\u5bb6\u65cf\u7684\u91cd\u8981\u6210\u5458\uff0c\u5b83\u51ed\u501f\u72ec\u7279\u7684\u7ed3\u6784\u548c\u591a\u6837\u5316\u7684\u529f\u80fd\uff0c\u5728\u73b0\u4ee3\u5316\u5b66\u5de5\u4e1a\u548c\u5b9e\u9a8c\u5ba4\u7814\u7a76\u4e2d\u5360\u636e\u4e86\u91cd\u8981\u5730\u4f4d\u3002\u672c\u6587\u5c06\u4ece\u591a\u4e2a\u89d2\u5ea6\u6df1\u5165\u63a2\u8ba8\u4e09\u57fa\u78f7\u5728\u5b9a\u5236\u5316\u9879\u76ee\u4e2d\u7684\u7075\u6d3b\u5e94\u7528\uff0c\u5e76\u7ed3\u5408\u56fd\u5185\u5916\u6587\u732e\u5bf9\u5176\u6027\u80fd\u8fdb\u884c\u5168\u9762\u5206\u6790\u3002<\/p>\n

\u4e00\u3001\u4e09\u57fa\u78f7\u7684\u57fa\u672c\u53c2\u6570\u4e0e\u7279\u6027<\/h2>\n

1.1 \u5206\u5b50\u7ed3\u6784\u6982\u8ff0<\/h3>\n

\u4e09\u57fa\u78f7\u7684\u5316\u5b66\u5f0f\u4e3aC18H15P\uff0c\u7531\u4e09\u4e2a\u73af\u901a\u8fc7\u5171\u4ef7\u952e\u8fde\u63a5\u5230\u4e00\u4e2a\u78f7\u539f\u5b50\u4e0a\u6784\u6210\u3002\u8fd9\u79cd\u7ed3\u6784\u8d4b\u4e88\u4e86\u5b83\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u4ee5\u53ca\u826f\u597d\u7684\u7535\u5b50\u4f20\u9012\u80fd\u529b\u3002\u4ee5\u4e0b\u662f\u5176\u4e3b\u8981\u7269\u7406\u5316\u5b66\u53c2\u6570\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n

\u53c2\u6570\u540d\u79f0<\/th>\n	\u6570\u636e\u503c<\/th>\n<\/tr>\n<\/thead>\n
\u5206\u5b50\u91cf<\/td>\n	262.30 g\/mol<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n	80-82\u00b0C<\/td>\n<\/tr>\n
\u6cb8\u70b9<\/td>\n	375\u00b0C<\/td>\n<\/tr>\n
\u5bc6\u5ea6<\/td>\n	1.08 g\/cm\u00b3<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n	\u5fae\u6eb6\u4e8e\u6c34\uff0c\u6613\u6eb6\u4e8e\u6709\u673a\u6eb6\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 1.2 \u7ed3\u6784\u4f18\u52bf\u5206\u6790<\/h3>\n \u4e09\u57fa\u78f7\u7684\u72ec\u7279\u4e4b\u5904\u5728\u4e8e\u5176\u5927\u4f4d\u963b\u6548\u5e94\u548c\u03c0\u7535\u5b50\u4e91\u5206\u5e03\u3002\u8fd9\u79cd\u7ed3\u6784\u7279\u70b9\u4f7f\u5f97\u5b83\u80fd\u591f\u6709\u6548\u5c4f\u853d\u78f7\u4e2d\u5fc3\u539f\u5b50\uff0c\u9632\u6b62\u4e0d\u5fc5\u8981\u7684\u526f\u53cd\u5e94\u53d1\u751f\uff0c\u540c\u65f6\u4fdd\u6301\u8f83\u9ad8\u7684\u6d3b\u6027\u3002\u6b63\u5982\u4e00\u4f4d\u8eab\u62ab\u94e0\u7532\u5374\u4f9d\u7136\u654f\u6377\u7684\u6218\u58eb\uff0c\u4e09\u57fa\u78f7\u5728\u590d\u6742\u7684\u5316\u5b66\u73af\u5883\u4e2d\u6e38\u5203\u6709\u4f59\u3002<\/p>\n \u4e8c\u3001\u4e09\u57fa\u78f7\u7684\u591a\u529f\u80fd\u89d2\u8272<\/h2>\n 2.1 \u50ac\u5316\u5242\u4e2d\u7684\u8868\u73b0<\/h3>\n \u5728\u50ac\u5316\u9886\u57df\uff0c\u4e09\u57fa\u78f7\u5e38\u5e38\u4e0e\u5176\u4ed6\u91d1\u5c5e\u914d\u5408\u5f62\u6210\u9ad8\u6548\u7684\u50ac\u5316\u5242\u4f53\u7cfb\u3002\u4f8b\u5982\uff0c\u5728Wittig\u53cd\u5e94\u4e2d\uff0c\u5b83\u4e0e\u78b1\u91d1\u5c5e\u6c27\u5316\u7269\u534f\u540c\u4f5c\u7528\uff0c\u4fc3\u8fdb\u70ef\u70c3\u7684\u751f\u6210\u3002\u8fd9\u4e00\u8fc7\u7a0b\u5c31\u50cf\u662f\u642d\u5efa\u4e00\u5ea7\u6865\u6881\uff0c\u8ba9\u539f\u672c\u96be\u4ee5\u76f8\u9047\u7684\u53cd\u5e94\u7269\u987a\u5229\u7ed3\u5408\u3002<\/p>\n \u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55<\/h4>\n \u6839\u636e\u56fd\u5916\u6587\u732e\u62a5\u9053\uff0c\u4e09\u57fa\u78f7\u5728\u94af\u50ac\u5316\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u8272\u3002\u5b83\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u53cd\u5e94\u7684\u9009\u62e9\u6027\uff0c\u8fd8\u663e\u8457\u964d\u4f4e\u4e86\u50ac\u5316\u5242\u7528\u91cf\u3002\u56fd\u5185\u7814\u7a76\u5219\u8fdb\u4e00\u6b65\u53d1\u73b0\uff0c\u901a\u8fc7\u8c03\u8282\u53cd\u5e94\u6761\u4ef6\uff0c\u53ef\u4ee5\u5b9e\u73b0\u5bf9\u4ea7\u7269\u533a\u57df\u9009\u62e9\u6027\u7684\u7cbe\u786e\u63a7\u5236\u3002<\/p>\n\n\n\n\n\n\n\n \u53cd\u5e94\u7c7b\u578b<\/th>\n \u4f18\u70b9\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n Wittig\u53cd\u5e94<\/td>\n \u63d0\u9ad8\u8f6c\u5316\u7387\uff0c\u51cf\u5c11\u526f\u4ea7\u7269<\/td>\n<\/tr>\n Heck\u53cd\u5e94<\/td>\n \u589e\u5f3a\u5e95\u7269\u517c\u5bb9\u6027\uff0c\u6269\u5927\u9002\u7528\u8303\u56f4<\/td>\n<\/tr>\n Suzuki\u53cd\u5e94<\/td>\n \u6539\u5584\u53cd\u5e94\u901f\u7387\uff0c\u964d\u4f4e\u80fd\u8017<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 2.2 \u914d\u4f53\u529f\u80fd\u7684\u53d1\u6325<\/h3>\n \u4f5c\u4e3a\u914d\u4f53\uff0c\u4e09\u57fa\u78f7\u80fd\u591f\u4e0e\u591a\u79cd\u91d1\u5c5e\u79bb\u5b50\u5f62\u6210\u7a33\u5b9a\u7684\u914d\u5408\u7269\u3002\u8fd9\u4e9b\u914d\u5408\u7269\u5728\u6750\u6599\u79d1\u5b66\u3001\u836f\u7269\u7814\u53d1\u7b49\u9886\u57df\u6709\u7740\u5e7f\u6cdb\u7684\u5e94\u7528\u524d\u666f\u3002<\/p>\n \u5b9e\u9645\u6848\u4f8b\u5206\u6790<\/h4>\n \u4ee5\u948c-\u4e09\u57fa\u78f7\u914d\u5408\u7269\u4e3a\u4f8b\uff0c\u5b83\u5728\u5149\u50ac\u5316\u6c34\u5206\u89e3\u5236\u6c22\u65b9\u9762\u5c55\u73b0\u4e86\u60ca\u4eba\u7684\u6548\u7387\u3002\u8fd9\u79cd\u914d\u5408\u7269\u5c31\u50cf\u4e00\u53f0\u9ad8\u6548\u80fd\u91cf\u8f6c\u6362\u5668\uff0c\u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u5316\u5b66\u80fd\uff0c\u4e3a\u7eff\u8272\u80fd\u6e90\u5f00\u53d1\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n\n\n\n\n\n\n\n \u5e94\u7528\u9886\u57df<\/th>\n \u7279\u70b9\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n \u5149\u50ac\u5316<\/td>\n \u9ad8\u6548\u7a33\u5b9a\uff0c\u73af\u5883\u53cb\u597d<\/td>\n<\/tr>\n \u836f\u7269\u9012\u9001<\/td>\n \u9776\u5411\u6027\u5f3a\uff0c\u526f\u4f5c\u7528\u5c0f<\/td>\n<\/tr>\n \u4f20\u611f\u68c0\u6d4b<\/td>\n \u7075\u654f\u5ea6\u9ad8\uff0c\u54cd\u5e94\u901f\u5ea6\u5feb<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n 2.3 \u5408\u6210\u52a9\u624b\u7684\u89d2\u8272<\/h3>\n \u5728\u6709\u673a\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u4e09\u57fa\u78f7\u5e38\u88ab\u7528\u4f5c\u8fd8\u539f\u5242\u6216\u4e2d\u95f4\u4f53\u3002\u5b83\u7684\u5f15\u5165\u5f80\u5f80\u80fd\u591f\u7b80\u5316\u5de5\u827a\u6d41\u7a0b\uff0c\u964d\u4f4e\u6210\u672c\u3002<\/p>\n \u5de5\u827a\u4f18\u5316\u5b9e\u4f8b<\/h4>\n \u67d0\u5236\u836f\u4f01\u4e1a\u5229\u7528\u4e09\u57fa\u78f7\u6539\u8fdb\u4e86\u4e00\u79cd\u6297\u764c\u836f\u7269\u7684\u5408\u6210\u8def\u7ebf\uff0c\u6210\u529f\u5c06\u603b\u6536\u7387\u4ece\u539f\u6765\u768440%\u63d0\u5347\u81f375%\u4ee5\u4e0a\u3002\u8fd9\u4e00\u7a81\u7834\u6027\u8fdb\u5c55\u4e0d\u4ec5\u8282\u7ea6\u4e86\u5927\u91cf\u539f\u6599\uff0c\u8fd8\u5927\u5e45\u7f29\u77ed\u4e86\u751f\u4ea7\u5468\u671f\u3002<\/p>\n\n\n\n\n\n\n\n\n\n\n \u5de5\u827a\u6539\u8fdb\u524d<\/th>\n \u5de5\u827a\u6539\u8fdb\u540e<\/th>\n<\/tr>\n<\/thead>\n \u603b\u6536\u7387<\/td>\n 40%<\/td>\n<\/tr>\n \u751f\u4ea7\u5468\u671f<\/td>\n 12\u5929<\/td>\n<\/tr>\n \u6210\u672c<\/td>\n \u8f83\u9ad8<\/td>\n<\/tr>\n \u603b\u6536\u7387<\/td>\n 75%+<\/td>\n<\/tr>\n \u751f\u4ea7\u5468\u671f<\/td>\n 8\u5929<\/td>\n<\/tr>\n \u6210\u672c<\/td>\n \u663e\u8457\u964d\u4f4e<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \u4e09\u3001\u4e09\u57fa\u78f7\u7684\u6311\u6218\u4e0e\u673a\u9047<\/h2>\n \u5c3d\u7ba1\u4e09\u57fa\u78f7\u5177\u6709\u8bf8\u591a\u4f18\u70b9\uff0c\u4f46\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\u4e5f\u9762\u4e34\u7740\u4e00\u4e9b\u6311\u6218\u3002\u4f8b\u5982\uff0c\u5176\u8f83\u9ad8\u7684\u4ef7\u683c\u9650\u5236\u4e86\u5927\u89c4\u6a21\u63a8\u5e7f\uff1b\u6b64\u5916\uff0c\u67d0\u4e9b\u7279\u6b8a\u6761\u4ef6\u4e0b\u53ef\u80fd\u4f1a\u4ea7\u751f\u6bd2\u6027\u526f\u4ea7\u7269\u3002<\/p>\n 3.1 \u6280\u672f\u9769\u65b0\u5e26\u6765\u7684\u5e0c\u671b<\/h3>\n \u8fd1\u5e74\u6765\uff0c\u968f\u7740\u5408\u6210\u6280\u672f\u7684\u8fdb\u6b65\uff0c\u4f4e\u6210\u672c\u4e09\u57fa\u78f7\u751f\u4ea7\u5de5\u827a\u9010\u6e10\u6210\u719f\u3002\u8fd9\u65e0\u7591\u4e3a\u672a\u6765\u66f4\u5e7f\u6cdb\u7684\u5e94\u7528\u5960\u5b9a\u4e86\u57fa\u7840\u3002\u540c\u65f6\uff0c\u79d1\u5b66\u5bb6\u4eec\u4e5f\u5728\u79ef\u6781\u63a2\u7d22\u66ff\u4ee3\u54c1\u6216\u6539\u6027\u65b9\u6848\uff0c\u529b\u6c42\u5728\u4fdd\u6301\u6027\u80fd\u7684\u540c\u65f6\u964d\u4f4e\u6210\u672c\u3002<\/p>\n 3.2 \u73af\u4fdd\u4e0e\u5b89\u5168\u8003\u91cf<\/h3>\n \u9762\u5bf9\u73af\u4fdd\u538b\u529b\uff0c\u7814\u7a76\u4eba\u5458\u6b63\u5728\u52aa\u529b\u5f00\u53d1\u66f4\u52a0\u7eff\u8272\u7684\u4e09\u57fa\u78f7\u76f8\u5173\u4ea7\u54c1\u3002\u901a\u8fc7\u4f18\u5316\u53cd\u5e94\u8def\u5f84\uff0c\u51cf\u5c11\u5e9f\u5f03\u7269\u6392\u653e\uff0c\u786e\u4fdd\u6574\u4e2a\u751f\u547d\u5468\u671f\u5185\u7684\u53ef\u6301\u7eed\u53d1\u5c55\u3002<\/p>\n \u56db\u3001\u7ed3\u8bed<\/h2>\n \u4e09\u57fa\u78f7\u4f5c\u4e3a\u5b9a\u5236\u5316\u9879\u76ee\u4e2d\u7684\u5173\u952e\u5206\u5b50\uff0c\u51ed\u501f\u5176\u5353\u8d8a\u7684\u7075\u6d3b\u6027\u548c\u591a\u529f\u80fd\u6027\u8d62\u5f97\u4e86\u4e1a\u754c\u7684\u9ad8\u5ea6\u8ba4\u53ef\u3002\u65e0\u8bba\u662f\u4f5c\u4e3a\u50ac\u5316\u5242\u3001\u914d\u4f53\u8fd8\u662f\u5408\u6210\u52a9\u624b\uff0c\u5b83\u90fd\u5c55\u73b0\u51fa\u4e86\u975e\u51e1\u7684\u4ef7\u503c\u3002\u5f53\u7136\uff0c\u6211\u4eec\u4e5f\u5e94\u8be5\u6b63\u89c6\u5f53\u524d\u5b58\u5728\u7684\u95ee\u9898\uff0c\u4e0d\u65ad\u5bfb\u6c42\u521b\u65b0\u89e3\u51b3\u65b9\u6848\uff0c\u8ba9\u8fd9\u4f4d\u5316\u5b66\u754c\u7684\u201c\u591a\u9762\u624b\u201d\u5728\u672a\u6765\u53d1\u6325\u66f4\u5927\u7684\u4f5c\u7528\u3002<\/p>\n \u53c2\u8003\u6587\u732e\uff1a \n[1] Smith J., et al. Advances in Triphenylphosphine Catalysis, Journal of Organic Chemistry, 2019. \n[2] \u5f20\u4f1f\u660e, \u674e\u7ea2\u6885. \u4e09\u57fa\u78f7\u53ca\u5176\u884d\u751f\u7269\u7684\u7814\u7a76\u8fdb\u5c55, \u5316\u5b66\u901a\u62a5, 2020. \n[3] Green Chemistry Initiatives for Triphenylphosphine Derivatives, Environmental Science & Technology, 2021.<\/p>\n \u5728\u8fd9\u4e2a\u5145\u6ee1\u53ef\u80fd\u6027\u7684\u65f6\u4ee3\uff0c\u8ba9\u6211\u4eec\u4e00\u8d77\u671f\u5f85\u4e09\u57fa\u78f7\u5e26\u6765\u66f4\u591a\u60ca\u559c\u5427\uff01😊<\/p>\n \u6269\u5c55\u9605\u8bfb:https:\/\/www.cyclohexylamine.net\/high-quality-nn-dicyclohexylmethylamine-cas-7560-83-0\/<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/polycat-35-catalyst-cas25441-67-9-evonik-germany\/<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/206<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/wp-content\/uploads\/2020\/06\/66.jpg<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/39844<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/lupragen-n105-catalyst-cas109-02-4-basf\/<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.newtopchem.com\/archives\/1089<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/dmea\/<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.cyclohexylamine.net\/coordinated-thiol-methyltin-methyl-tin-mercaptide\/<\/a><\/br> \u6269\u5c55\u9605\u8bfb:https:\/\/www.bdmaee.net\/nt-cat-da-20-catalyst-cas11125-17-8-newtopchem\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":" \u4e09\u57fa\u78f7\u7684\u7075\u6d3b\u6027\u5206\u6790\uff1a\u5b9a\u5236\u5316\u9879\u76ee\u4e2d\u7684\u660e\u661f\u5206\u5b50 \u5728\u5316\u5b66\u4e16\u754c\u91cc\uff0c\u4e09\u57fa\u78f7\uff08Triphenylphosphine\uff09\u5c31\u50cf\u4e00\u4f4d\u591a\u624d\u591a\u827a\u7684\u827a\u672f\u5bb6\uff0c\u65e2\u80fd\u626e\u6f14\u6e29\u548c\u7684\u50ac\u5316\u5242\uff0c\u53c8\u80fd\u5316\u8eab\u4e3a\u5f3a\u5927\u7684\u914d\u4f53\uff0c\u8fd8\u80fd\u6210\u4e3a\u5408\u6210\u53cd\u5e94\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u5e2e\u624b\u3002\u4f5c\u4e3a\u6709\u673a\u78f7\u5316\u5408\u7269\u5bb6\u65cf\u7684\u91cd\u8981\u6210\u5458\uff0c\u5b83\u51ed\u501f\u72ec\u7279\u7684\u7ed3\u6784\u548c\u591a\u6837\u5316\u7684\u529f\u80fd\uff0c\u5728\u73b0\u4ee3\u5316\u5b66\u5de5\u4e1a\u548c\u5b9e\u9a8c\u5ba4\u7814\u7a76\u4e2d\u5360\u636e\u4e86\u91cd\u8981\u5730\u4f4d\u3002\u672c\u6587 …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[4],"tags":[],"_links":{"self":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/10502"}],"collection":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/comments?post=10502"}],"version-history":[{"count":0,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/posts\/10502\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/media?parent=10502"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/categories?post=10502"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51dmea.cn\/wp-json\/wp\/v2\/tags?post=10502"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}